UN 2599Chlorotrifluoromethane and trifluoromethane azeotropic mixture or Refrigerant gas R 503 with approximately 60 percent chlorotrifluoromethane
Division 2.2
Non-flammable, non-toxic gases
Summary
UN 2599 is the UN number for chlorotrifluoromethane and trifluoromethane azeotropic mixture or Refrigerant gas R 503 with approximately 60 percent chlorotrifluoromethane. It is classed in Division 2.2 (non-flammable, non-toxic gases) of Class 2 for transport. Emergency responders use ERG guide 126.
Emergency response
The Emergency Response Guidebook (ERG2024) guide for this number:
- Guide126Chlorotrifluoromethane and trifluoromethane azeotropic mixture with approximately 60% chlorotrifluoromethaneRefrigerant gas R-503
From the 2024 Emergency Response Guidebook (ERG2024), published by U.S. Department of Transportation, PHMSA. Read the full guide in the ERG or on CAMEO Chemicals.
Identification
- UN number
- UN 2599
- Name
- Chlorotrifluoromethane and trifluoromethane azeotropic mixture or Refrigerant gas R 503 with approximately 60 percent chlorotrifluoromethane
- Hazard class
- Class 2: Gases
- Division
- 2.2: Non-flammable, non-toxic gases
- What the class covers
- Gases which are neither flammable nor toxic, including asphyxiant and oxidizing gases.
U.S. Hazardous Materials Table
The entry for this number in 49 CFR 172.101.
UN2599Chlorotrifluoromethane and trifluoromethane azeotropic mixture or Refrigerant gas R 503
with approximately 60 percent chlorotrifluoromethane
- Class
- 2.2
- Packing group
- None
- Labels
- 2.2
From the eCFR edition of 49 CFR 172.101 dated 2026-10-05 (section last amended 2026-09-08). The eCFR is an editorial compilation, not the official legal edition. Read the current table.
About Class 2
Class 2 covers gases, whether compressed, liquefied, dissolved under pressure or refrigerated. Division 2.1 is flammable gases such as propane, 2.2 is non-flammable, non-toxic gases such as nitrogen, and 2.3 is toxic gases such as chlorine.
Check the official sources
For emergency response, packaging and quantity limits, use these:
- CAMEO Chemicals: UN/NA 2599NOAA datasheets with the ERG response guide and isolation distances
- Emergency Response Guidebook (ERG)PHMSA's guide for first responders, free as a PDF or app
- 49 CFR 172.101 Hazardous Materials TableThe legal U.S. entry: proper shipping name, packing group, labels and special provisions